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Chirico, Robert D. ; Kazakov, Andrei F. Highlights: • Heat capacities were measured for the temperature range (5 to 520) K. • The enthalpy of combustion was measured and the enthalpy of formation was derived. Theory and results of the study of partitioning of elements in coexisting minerals are briefly reviewed. Understanding conceptual components of the enthalpy of solution formula. Souza Freitas, R. de. • Mechanical stability is testified from elastic constants at zero pressure.

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Basic Terms Crossword Puzzle. Abstract: In order to optimize the crystallization process of creatine monohydrate, the solubility of creatine monohydrate in the binary (water + ethanol) mixture was measured at temperatures ranging from 278. Physicochemical details like the size, the electronic charge distribution and the geometry of amphiphile molecules as well as third-order derivatives of the Gibbs energy and the associated Koga lines support the above claims while they further contribute to characterizing the role of hydrophobicity in these phenomena. This article examines différent approaches ta the thermodynamics of polymer solutions set in their historical context. In addition, we find that the structural properties of those peptides are different from each other in the gas phase and in aqueous solution. Chirico, Robert D. ; Steele, William V. ; Kazakov, Andrei F. Highlights: • Heat capacities were measured for the temperature range (5 to 445) K. • Vapor pressures were measured for the temperature range (338 to 495) K. Understanding conceptual components of the enthalpy of solution aleks. • Densities at saturation pressure were measured from T = (323 to 523) K. • Computed and experimentally derived properties for ideal gas entropies are in excellent accord. Full Text Available In a recent work, we present a new point of view to the relation of gravity and thermodynamics, in which we derive the Schwarzschild solution through thermodynamic considerations by the aid of the Misner–Sharp mass in an adiabatic system. We show how one can determine an effective interaction potential between the proteins from experimental data as a function of salt concentration and we apply this to the. Electrolytes are used as working fluids in gas-fired heat pump-chiller engine cycles. In initial state, DUPIC fuel which contains fissile materials is different from general nuclear fuel. Since both versions of thermodynamics are different only in their treatment of antimatter, but are the same in describing our world dominated by matter, making a clear experimentally justified choice between CP invariance and CPT invariance in context of thermodynamics is not possible at present. A correlation based on both liquid and a gas phase variable for carbon dioxide absorption rate was presented using the π-Buckingham theorem. Although the method is applied to HS model, it is readily extended to more complex hard-body potentials, such as hard tetrahedra. The CTserver platform is an Internet-based computational resource that provides on-demand services in Computational Thermodynamics (CT) to a diverse geoscience user base.

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Two ternary systems, Mg-Cu-Ni and Cd-Bi-Pb are recalculated to demonstrate the validity and precision of the present model. Accurate experimental data of fluid properties and theoretical approach from the intermolecular potential were simultaneously considered in the development to insure accuracy and to improve reliability of the equation of state over wide range of pressures and temperatures. Sadeghi, Rahmat; Shekaari, Hemayat; Hosseini, Rahim. Abstract: The density, sound velocity, and conductivity measurements were performed on aqueous solutions of sodium dodecyl sulfate (C{sub 12}H{sub 25}SO{sub 4}Na) or sodium dodecyl sulfonate (C{sub 12}H{sub 25}SO{sub 3}Na) in the absence and presence of poly(ethylene glycol) (PEG) at different temperatures. Thermodynamic properties of fluids are of key importance for the chemical industry. Additionally, some of the thermodynamic properties which can help to evaluate its dissolution behavior were obtained based on the NRTL model. Accordingly, the objective of this report is to rearrange systematically the existing thermodynamic data based on metal fluorides and is to use it as basic data for the development of pyrochemical process. Understanding conceptual components of the enthalpy of solution definition. Assuming that the dark energy temperature T∼a -n and considering that the volume of the Universe enveloped by the apparent horizon relates to the temperature, we have derived the dark energy entropy. Abstract: This work presents a comprehensive experimental and computational study of the thermodynamic properties of 2, 7-di-tert-butylfluorene. These significant dynamical properties dependent on the softness parameter (n) are consistent to dynamical behavior observed in liquid alkali metals and liquefied inert gases.

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Differences between thermodynamic... Xiong, Shiyun; Qi, Weihong; Cheng, Yajuan; Huang, Baiyun; Wang, Mingpu; Li, Yejun. The results thus obtained for the bulk moduli are quite satisfactory. • Heat capacity, entropy. The solubility increased with both the temperature and the mole fraction of water in the solvent mixture. The previous model on surface free energy has been extended to calculate size dependent thermodynamic properties (i. e., melting temperature, melting enthalpy, melting entropy, evaporation temperature, Curie temperature, Debye temperature and specific heat capacity) of nanoparticles. With both existence of the magnetic anisotropy and transverse field, we have studied effects of them on the magnetic properties and the thermodynamics. Guencheva, V. ; Grantscharova, E. ; Gutzow, I. Examination of the protein crystallization process involves investigation of the liquid and solid state and a protein's properties in these states. Interestingly, the entropy of a black hole is barely affected and still obeys the standard area law. First-principles calculations were completed on the intermetallic and solution phases. Black-Right-Pointing-Pointer Cooperativity of H-bonds in methanol media is smaller than in water solutions. In this work, its contributions to aqueous density, apparent molal volume, vapour pressure and thermodynamic water activity values, derived from in-house experiments, are reported.

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The calculated internal energy data and the calculated values of isobaric heat capacity of molten potassium show the minimum along the isothermal lines as the previous result obtained in liquid sodium. Despite a zero heat of mixing, the solid solution is not ideal in that activities do not obey Raoult's Law because of the more complex entropy of mixing. Theoretical estimates made in terms of Ostwald's Rule of Stages indicate that in processes of metastable isothermal diamond synthesis additional kinetic factors (e. influencing the formation of sp{sup 3} - carbon structures in the ambient phase) and the introduction of active substrates (e. diamond powder) are to be of significance in the realization of this thermodynamic possibility. Properties of the general relativistic kink solution of a nonlinear scalar field recently obtained, are discussed. For certain Nb/V ratios Henry's law is obeyed for concentrations as high as 6. Some examples of them are discussed and illustrated at the end of the report.

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• The extrapolation based on only binary interaction parameters leads to a good agreement with the data on the ternary. 15 to 5000 K for molybdenum. The phases, including liquid and bcc A 2(βPr) were treated as substitutional solutions, while the intermetallic compounds, including PrZn, PrZn 2, PrZn 3, Pr 3 Zn 11, Pr 13 Zn 58, Pr 3 Zn 22, Pr 2 Zn 17 and PrZn 11 were modeled as stoichiometric compounds. It was shown that the impact on the open circuit voltage would be minor. An IAPWS release points out that this new formulation has some unsatisfactory features in the immediate vicinity of the critical point. The thermodynamic properties are then estimated with the Multistate Bennett Acceptance Ratio (MBAR) as a function of multiple model parameters without the need to define a priori how the states are connected by a pathway. Our theory reveals a relationship between the microscopic structure parameters of electrolyte solutions and the macroscopic thermodynamic properties, which is applied to concentrated electrolyte solutions. We construct a new class of charged rotating solutions of (n+1)-dimensional Einstein-Born-Infeld gravity with cylindrical or toroidal horizons in the presence of cosmological constant and investigate their properties. Moreover, examination of the esters' enthalpy values allowed a probable conformation adopted by ethyl octanoate in aqueous solution to be proposed. Vargaftik, N. B. ; Voljak, L. ; Stepanov, V. G. 1985-01-01. Quantities like Hawking temperature and entropy of the black holes are computed. Thu... Ana Perederic, Olivia; Cunico, Larissa; Sarup, Bent. The thermodynamic studies indicate that the adsorption of DOX on GO is spontaneous and endothermic in nature.

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Kritskaya, E. ; Burylev, B. ; Mojsov, L. ; Kritskij, V. E. Relaying on the experimentally ascertained linear dependence of the Gibbs excessive mole energies on alkali metal ordinal number in the systems MnBr 2 -MBr (M=Na, K, Rb), thermodynamic properties of the melts in binary systems MBr 2 -M'Br (M'=Li, Cs, Fr) were prepared. Heat of solution of the Sr x Ca 1-x NdAlO 4 samples in molten 2PbO. The use of monoethanolamine is most promising to obtain chemisorbents because the thermodynamic functions of its onium cation acid-base dissociation are least dependent on temperature compared to other etanolammonium cations. Hiadsi S. Full Text Available The results of first-principles theoretical study of structural, elastic, electronic and thermodynamic properties of KTaO3 compound, have been performed using the full-potential linear augmented plane-wave method plus local orbitals (FP-APW+lo as implemented in the Wien2k code. This work investigates the comparative properties of the CP- and CPT-invariant extensions of thermodynamics (focusing on the latter, which is less conventional than the former and examines conditions under which these extensions can be experimentally tested. The book begins by clarifying basic concepts for stable crystals. Finally, table 4 gathers the data relative to species in aqueous solution. The isopiestic measurements reported here simultaneously reflect two fundamental properties of the system, i. e., the activity of water as a function of solution concentration and the occurrence of solid-liquid transitions. Zhang, Chiqian; Brown, Pamela J B; Hu, Zhiqiang. It has been shown that the kink solution is stable against radical perturbations. Relationships fitted to the experimental data are presented and discussed, with the aim of determining a consistent set of thermodynamic properties (enthalpy, heat capacity) for the systems Li-(LiH, LiD, LiT) in the solid state and in the melt. The Lennard-Jones intermolecular potential was used. Comparisons between calculated and measured phase diagrams show that most of the experimental information is satisfactorily accounted for by thermodynamic calculations. The free energy of formation of alpha-Mo2C is determined from the activity data.

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Calculations of the values of C(o)p. 2 and V2(0) for several polypeptides have been carried out to test the predictive utility of the HKF group additivity model. This debate culminated in the development of linear response. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of non-equilibrium entropy, a fundamental equation of state in the entropy representation, and a fluctuation postulate describing the probability distribution of macroscopic parameters of an isolated system. According to these authors, it is namely important to reach the equilibrium from both under and over saturation and to characterize from a mineralogical point of view the end products. It is shown that compositions of amorphous alloys prepared by melt quenching coincide with the ranges of concentration with the predominance of Fe3Er and FeEr2 associative groups that have large negative entropies of formation. The thermodynamic properties of secondary phases observed to form during nuclear waste glass-water interactions are of particular interest as it is with the application of these properties together with the thermodynamic properties of other solid phases, fluid phases, and aqueous species that one may predict the environmental consequences of introducing radionuclides contained in the glass into groundwater at a high-level nuclear waste repository. The calculated H-bond energy was 10. Abstract: Measurements leading to the calculation of thermodynamic properties for 9-fluorenone (IUPAC name 9H-fluoren-9-one and Chemical Abstracts registry number [486-25-9]) in the ideal-gas state are reported. Delgado, Daniel R. ; Martínez, Fleming; Gutiérrez, Rahumir A. Brewer, L. ; Lamoreaux, R. H. ; California Univ., Berkeley. The golden dream of any modeling enterprise is to predict the properties of the studied system in a new and often 'hostile' environment. Recent additions include Duan, Møller and Weare's model for supercritical C-O-H-S, extended to include SO2 and S2 species, and an entirely new associated solution model for O-S-Fe-Ni sulfide liquids.

Wu, R. ; Lee, L. ; Cochran, D. This paper exhibits on the molecular level, the relationships between the microscopic structure and thermodynamic properties of dilute supercritical solutions by application of the integral equation theories for molecular distribution functions. Quantum chemical calculations and spectroscopic measurements of spectroscopic and thermodynamic properties of given uranyl complexes in aqueous solutions with possible environmental and industrial applications. Furthermore, our investigation indicate that Al-Ga binary alloy have a tendency to exhibit ideal mixture behaviour in the concentration range 0≤c Al ≤0. The vibrational, thermodynamical, and optical properties are theoretically estimated for the first time. Thermodynamic functions of melts were described by the associated solution model. We solve in closed form the simplest (su(1|1)) supersymmetric version of Inozemtsev's elliptic spin chain, as well as its infinite (hyperbolic) counterpart. Such modelling can reproduce the short range structure of protein solutions at equilibrium and predict thermodynamics instabilities of these systems.

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